di-pimethane rearrangement
di-pimethane rearrangement noun: a photochemical reaction of a molecular entity comprising two p-systems, separated by a saturated carbon atom (a 1,4-diene or an allyl-substituted aromatic analog), to form an ene- (or aryl-) substituted cyclopropane. The rearrangement formally amounts to a 1,2 shift of one ene group (in the diene) or the aryl group (in the allyl-aromatic analog) and ‘bond formation’ between the lateral carbons of the non-migrating moiety.
Noun
di-pimethane rearrangement (plural di-pimethane rearrangements)
- A photochemical reaction of a molecular entity comprising two p-systems, separated by a saturated carbon atom (a 1,4-diene or an allyl-substituted aromatic analog), to form an ene- (or aryl-) substituted cyclopropane. The rearrangement formally amounts to a 1,2 shift of one ene group (in the diene) or the aryl group (in the allyl-aromatic analog) and ‘bond formation’ between the lateral carbons of the non-migrating moiety.
Forms of di-pimethane rearrangement
| plural | di-pimethane rearrangements |
|---|---|
| alternative form | di-pi-methane rearrangement |
| alternative form | di-π-methane rearrangement |
Questions about di-pimethane rearrangement
- What does di-pimethane rearrangement mean?
- Di-pimethane rearrangement means a photochemical reaction of a molecular entity comprising two p-systems, separated by a saturated carbon atom (a 1,4-diene or an allyl-substituted aromatic analog), to form an ene- (or aryl-) substituted cyclopropane. The rearrangement formally amounts to a 1,2 shift of one ene group (in the diene) or the aryl group (in the allyl-aromatic analog) and ‘bond formation’ between the lateral carbons of the non-migrating moiety.
- What part of speech is di-pimethane rearrangement?
- Di-pimethane rearrangement is a noun.
- What is the plural of di-pimethane rearrangement?
- The plural of di-pimethane rearrangement is di-pimethane rearrangements.
Words near di-pimethane rearrangement in the dictionary
Source and license
Adapted from Wiktionary: di-pimethane rearrangement (page history and authors). Text available under the Creative Commons Attribution-ShareAlike 4.0 license. Word.ws reformatted the entry and added links. Wiktionary data of 2026-09-02.
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Cite this entry: “di-pimethane rearrangement.” Word.ws, https://word.ws/di-pimethane_rearrangement. Based on Wiktionary, CC BY-SA 4.0.
