Tsuji-Trost reaction
Tsuji-Trost reaction noun: a palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product.
Noun
Tsuji-Trost reaction (plural Tsuji-Trost reactions)
- A palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product.
Forms of Tsuji-Trost reaction
| plural | Tsuji-Trost reactions |
|---|
Origin of Tsuji-Trost reaction
Pioneered by Jiro Tsuji in 1965 and later adapted by Barry Trost in 1973 with the introduction of phosphine ligands.
Questions about Tsuji-Trost reaction
- What does Tsuji-Trost reaction mean?
- Tsuji-Trost reaction means a palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product.
- What part of speech is Tsuji-Trost reaction?
- Tsuji-Trost reaction is a noun.
- What is the plural of Tsuji-Trost reaction?
- The plural of Tsuji-Trost reaction is Tsuji-Trost reactions.
Words near Tsuji-Trost reaction in the dictionary
Source and license
Adapted from Wiktionary: Tsuji-Trost reaction (page history and authors). Text available under the Creative Commons Attribution-ShareAlike 4.0 license. Word.ws reformatted the entry and added links. Wiktionary data of 2026-09-02.
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Cite this entry: “Tsuji-Trost reaction.” Word.ws, https://word.ws/tsuji-trost_reaction. Based on Wiktionary, CC BY-SA 4.0.
